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This is the full version of X-plorer Dash 8 - The Windows Explorer replacement.. and Windows Explorer Assistant.Enantioselective Pt-Catalyzed Regioselective and Diastereoselective Trifluoromethylation of Chiral Olefins.
Pt-Catalyzed trifluoromethylation of chiral olefins was developed. As chiral ligands, some 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) derivatives were tested in the catalytic process. An optically active binaphthyl-based chiral phosphine was found to be much more efficient for the asymmetric trifluoromethylation of chiral olefins compared to other BINAP derivatives. The chiral ligand structure and structure of the chiral Pt catalyst also exerted obvious influences on the regioselectivity and enantioselectivity of the trifluoromethylation reaction.Myosin II is required for stem cell-mediated endocardial cushion morphogenesis in zebrafish.
The zebrafish has emerged as a powerful model system to study the molecular mechanisms that control cardiac development. Endocardial cells (EnC) form a cord-like structure that overlies the inflow tract and divides to produce the mature cardiac valves. Several transcriptional regulators including Nkx2.5 and Gata6 have been shown to control morphogenesis and function of EnC. In this study, we investigated the role of myosin II in EnC morphogenesis using zebrafish embryos with reduced myosin II activity. Knockdown of myosin II using a MO of myosin II function, smas or sqh, specifically resulted in defects in the EnC morphogenesis and morphology. These defects included the absence or severe malformation of the endocardial cushion, disruption of cardiomyocyte morphology, and the 0b46394aab
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